Although apple juice is a healthy, and often preferred, alternative to artificially flavored and carbonated drinks for many parents to give to children, concern has been raised over the presence of arsenic within. This work demonstrates a reversed-phase ion-pairing method for the complete separation and accurate quantification of the main and most toxicologically relevant arsenic species in commercially available apple juices, using a PerkinElmer NexSAR HPLC-ICP-MS system.